CHEMICAL FACT SHEET for emergency responders

 

CHEMICAL:

Sulfuric Acid

 

H2SO4

1830

7664-93-9

137

yes

yes

1000#

3

0

2

Chemical Formula

UN #

C.A.S. #

ERG . #

Hazardous Substance

Extremely Hazardous Substance

RQ

Health

Fire

Reactivity

 

Characteristics

Exposure Limits

 

Common Uses

Appearance:

Clear colorless solution

LEL:

N/A

 

Battery Acid, Oil of Vitriol, fertilizer acid

Catalyst in petrochemical processing

 

 

 

 

 

UEL:

N/A

Specific Gravity:

1.07

IDLH:

15mg/m3

Flash Point:

N/A

STEL:

3mg/m3

Auto Ignition Temp.

N/A

PEL:

1mg/m3

Vapor Pressure:

N/A

 

 

pH:

2.1

 

 

 

 

 

 

 

Emergency Response PPE (Fire Fighters)

 

Hazards

Respiratory: 

Harmful if inhaled.  Wear positive pressure SCBA or airline.

 

Reacts violently with water, giving exothermic reaction

Reacts exothermically with organic materials (wood)

Can react with metal storage container, causing build-up of hydrogen in vapor space.

Corrosive to skin and many metals

Eye/Face/Body: 

Chemical protective clothing required, including rubber gloves & boots

                          

 

 

 

 

 

Emergency Medical Actions

 

Incompatible

 

Contact physician – observe for delayed pulmonary action

Do not induce vomiting, give large amounts of water if conscious

For eyes and skin, flush with copious amount of water for at least 15 minutes, do not use

      Oils or ointments

If ingested, do not perform mouth-to-mouth breathing

 

 

Water, metals, organic materials

 

 

 

 

 

Notes

 

Initial and Protective Action Distances

 

 

 

 

Small Spills <>

Dry earth, sand, lime or soda ash.

Restrict entry to those necessary

 

 

Large Spills <>

Evacuate downwind for at least 250 meters (800 ft)

If vapor cloud already exists, consider sheltering in place.

 

 

 

Emergency Response Actions

Medium expansion foams can be used to suppress vapors.

Do not use water on liquid.  However vapors can be contained/redirected with fog streams.  Runoff water may become acidic.

If container is involved in fire, cool the vapor space with large amounts of water.